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Tag: Sandia National Laboratories

  • Making materials more durable through science

    Making materials more durable through science

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    BYLINE: Kim Vallez Quintana

    Newswise — ALBUQUERQUE, N.M. — A team at Sandia National Laboratories developed a molecule that helps change the way some materials react to temperature fluctuations, which makes them more durable. It’s an application that could be used in everything from plastic phone cases to missiles.

    Polymers, which include various forms of plastics, are made up of many smaller molecules, bonded together. This bond makes them especially strong and an ideal product to be used to protect delicate components in a wide variety of items. But with time, use and exposure to different environments, all materials begin to deteriorate.

    Hot to cold, cold to hot, the big problem

    One of the biggest factors in materials deterioration is repeated exposure from hot to cold temperatures and back. Most materials expand when heated and contract when cooled, but each material has its own rate of change. Polymers, for example, expand and contract the most, while metals and ceramics contract the least.

    Erica Redline, a materials scientist who leads the team, said most items are made up of more than one kind of material.

    “Take for example, your phone, which has a plastic housing, coupled to a glass screen, and inside that, the metals and ceramics that make up the circuitry,” Redline said. “These materials are all screwed, glued or somehow bonded together and will start expanding and contracting at different rates, putting stresses on one another which can cause them to crack or warp over time.”

    Redline said she kept hearing the same complaint from Sandia’s many customers.

    “They’re always talking about thermal expansion mismatch problems and how their existing systems are hard to work with because of all the filler they need to add to compensate,” Redline said.

    With that, Redline’s idea was born.

    “I thought, what if I conjured up a perfect material, what would that look like,” Redline said.

    Redline thinks she’s done it, with the help of her team Chad Staiger, Jason Dugger, Eric Nagel, Koushik Ghosh, Jeff Foster, Kenneth Lyons, Alana Yoon and academic alliance collaborators Professor Zachariah Page and graduate student Meghan Kiker.

    The molecule in action

    The team modified a molecule so that it can easily be incorporated into a polymer to change its properties.

    “This really is a unique molecule that when you heat it up, instead of it expanding, it actually contracts by undergoing a change in its shape,” Redline said.

    “When it’s added to a polymer, it causes that polymer to contract less, hitting expansion and contraction values similar to metals. To have a molecule that behaves like metal is pretty remarkable.”

    Endless possibilities

    This molecule could be used in endless ways. Polymers are used as protective coatings in electronics, communications systems, solar panels, automotive components, printed circuit boards, aerospace applications, defense systems, flooring and more.

    “The molecule not only solves current issues but significantly opens up design space for more innovations in the future,” said Jason Dugger, a Sandia chemical engineer who has been looking at potential applications, especially in defense systems.

    Another key to this invention is that it can be incorporated into different parts of a polymer at different percentages, in 3D printing.

    “You could print a structure with certain thermal behaviors in one area, and other thermal behaviors in another to match the materials in different parts of the item,” Dugger said.

    Another benefit is helping reduce the weight of materials by eliminating heavy fillers.

    “It would enable us to do things much lighter to save mass,” Dugger said. “That is especially important when launching a satellite, for example. Every gram we can save is huge.”

    Redline said she has also been approached by an epoxy formulator who believes this molecule could be incorporated into adhesives.

    The next step

    The team has only created this molecule in small quantities, but they are working to find a way to scale up production so that other Sandia researchers can test the molecule to fit mission needs.

    Chad Staiger, an organic chemist at Sandia, makes the molecule. He said it takes him about 10 days to make between 7-10 grams.

    “It’s unfortunately a long synthesis for this molecule,” Staiger said. “More steps equal more time and more money. You usually see five- to six-step syntheses in higher value materials such as pharmaceuticals. In polymers, the cheaper the better for wide scale adoption.”

    The team is working to reduce the steps using $100,000 in funding through Sandia’s technology maturation program, which helps ready products for the marketplace.

    “My role is to see if there is an easier way to make it at a commercial level,” said postdoc Eric Nagel. “There is nothing like it out there. I am really excited at the possibilities of what this technology can do and the applications that could be associated with this.”

    “It’s pretty phenomenal and pretty wide open,” Staiger said.

    Dugger agreed: “It really is a sky’s the limit kind of thing.”

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  • ‘Stunning’ discovery: Metals can heal themselves

    ‘Stunning’ discovery: Metals can heal themselves

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    Newswise — ALBUQUERQUE, N.M. — Scientists for the first time have witnessed pieces of metal crack, then fuse back together without any human intervention, overturning fundamental scientific theories in the process. If the newly discovered phenomenon can be harnessed, it could usher in an engineering revolution — one in which self-healing engines, bridges and airplanes could reverse damage caused by wear and tear, making them safer and longer-lasting.

    The research team from Sandia National Laboratories and Texas A&M University described their findings today in the journal Nature.

    “This was absolutely stunning to watch first-hand,” said Sandia materials scientist Brad Boyce.

    “What we have confirmed is that metals have their own intrinsic, natural ability to heal themselves, at least in the case of fatigue damage at the nanoscale,” Boyce said.

    Fatigue damage is one way machines wear out and eventually break. Repeated stress or motion causes microscopic cracks to form. Over time, these cracks grow and spread until — snap! The whole device breaks, or in the scientific lingo, it fails.

    The fissure Boyce and his team saw disappear was one of these tiny but consequential fractures — measured in nanometers.

    “From solder joints in our electronic devices to our vehicle’s engines to the bridges that we drive over, these structures often fail unpredictably due to cyclic loading that leads to crack initiation and eventual fracture,” Boyce said. “When they do fail, we have to contend with replacement costs, lost time and, in some cases, even injuries or loss of life. The economic impact of these failures is measured in hundreds of billions of dollars every year for the U.S.”

    Although scientists have created some self-healing materials, mostly plastics, the notion of a self-healing metal has largely been the domain of science fiction.

    “Cracks in metals were only ever expected to get bigger, not smaller. Even some of the basic equations we use to describe crack growth preclude the possibility of such healing processes,” Boyce said.

    Unexpected discovery confirmed by theory’s originator

    In 2013, Michael Demkowicz — then an assistant professor at the Massachusetts Institute of Technology’s department of materials science and engineering, now a full professor at Texas A&M — began chipping away at conventional materials theory. He published a new theory, based on findings in computer simulations, that under certain conditions metal should be able to weld shut cracks formed by wear and tear.

    The discovery that his theory was true came inadvertently at the Center for Integrated Nanotechnologies, a Department of Energy user facility jointly operated by Sandia and Los Alamos national laboratories.

    “We certainly weren’t looking for it,” Boyce said.

    Khalid Hattar, now an associate professor at the University of Tennessee, Knoxville, and Chris Barr, who now works for the Department of Energy’s Office of Nuclear Energy, were running the experiment at Sandia when the discovery was made. They only meant to evaluate how cracks formed and spread through a nanoscale piece of platinum using a specialized electron microscope technique they had developed to repeatedly pull on the ends of the metal 200 times per second.

    Surprisingly, about 40 minutes into the experiment, the damage reversed course. One end of the crack fused back together as if it was retracing its steps, leaving no trace of the former injury. Over time, the crack regrew along a different direction.

    Hattar called it an “unprecedented insight.”

    Boyce, who was aware of the theory, shared his findings with Demkowicz.

    “I was very glad to hear it, of course,” Demkowicz said. The professor then recreated the experiment on a computer model, substantiating that the phenomenon witnessed at Sandia was the same one he had theorized years earlier.

    Their work was supported by the Department of Energy’s Office of Science, Basic Energy Sciences; the National Nuclear Security Administration and the National Science Foundation.

    A lot remains unknown about the self-healing process, including whether it will become a practical tool in a manufacturing setting.

    “The extent to which these findings are generalizable will likely become a subject of extensive research,” Boyce said. “We show this happening in nanocrystalline metals in vacuum. But we don’t know if this can also be induced in conventional metals in air.”

    Yet for all the unknowns, the discovery remains a leap forward at the frontier of materials science.

    “My hope is that this finding will encourage materials researchers to consider that, under the right circumstances, materials can do things we never expected,” Demkowicz said.

    Sandia National Laboratories is a multimission laboratory operated by National Technology and Engineering Solutions of Sandia LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration. Sandia Labs has major research and development responsibilities in nuclear deterrence, global security, defense, energy technologies and economic competitiveness, with main facilities in Albuquerque, New Mexico, and Livermore, California.

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  • Labs Director to make historic visit to Navajo Nation
Building research, recruitment partnership with Navajo Technical University

    Labs Director to make historic visit to Navajo Nation Building research, recruitment partnership with Navajo Technical University

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    Newswise — ALBUQUERQUE, N.M. — On March 17, Sandia National Laboratories Director Dr. James Peery will make an historic visit to Navajo Technical University in Crownpoint, New Mexico, marking the first time a sitting national lab director has visited a tribal college or university. The event is designed to build on the growing partnership Sandia has started with NTU.

    What: Labs Director visits Navajo Technical University
    When: 
    Friday, March 17, 8:45 a.m. – 1:30 p.m.; visual highlights 10:30 a.m. – noon
    Where: 
    Navajo Technical University, Lowerpoint Rd. State Hwy 371, Crownpoint, NM, 87313
    RSVP: 
    Contact  to confirm attendance.
    NTU media contact: 

    The partnership is part of the National Nuclear Security Administration’s Minority Serving Institution Partnership Plan, which helps national labs partner with tribal colleges and universities that prepare students for technical careers in NNSA’s laboratories and production plants.

    Navajo Technical University is a tribally controlled postsecondary career and technical institution with a main campus in Crownpoint and two smaller campuses in Chinle and Teec Nos Pos, Arizona. NTU offers programs focusing on advanced manufactured metal parts, certification of 3D-printed metal parts, inspection methodologies and techniques, including equipment operation, and optical metrology, including testing and characterization of materials; all skills that can be beneficial to Sandia’s mission.

    In August 2018, with the help of Sandia, NTU obtained accreditation from the Accreditation Board of Engineering and Technology for its industrial engineering and electrical engineering programs. Having an ABET accreditation allows Sandia to hire NTU graduates. Prior to this, area students who wanted to pursue a career at the national labs would have to attend another ABET accredited university, such as the University of New Mexico, first.

    Over the next five years, Sandia will be working with NTU on an initiative to dramatically increase the number of Native American researchers in advanced manufacturing, power and energy engineering and other technology disciplines. The partnership will work to build the first electrical engineering masters and doctoral program at NTU. Sandia will provide internship opportunities to Native American engineering students at NTU, subject matter experts in electrical engineering disciplines in power and energy and technical assistance in power system dynamics and optimization.

    Sandia is also working with NTU to expand programs in other disciplines, including chemical and mechanical engineering.

    During the visit, Peery will meet with NTU leadership and get a firsthand look at its programs and how the partnership has helped NTU grow. He will also tour the advanced manufacturing and energy systems labs.

    Media is invited to attend the visit, see NTU facilities and speak with NTU and Sandia leadership.

      • 9:00 a.m.: Welcome, by NTU President Dr. Elmer Guy
      • 9:15 a.m.: Welcome by NTU provost Dr. Colleen Bowman
      • 9:45 a.m.: Sandia National Laboratories Director address – Dr. James Peery
      • 10:50 a.m.: Advanced Manufacturing tour
      • 11:30 a.m.: Energy Systems Lab tour
      • 12:00 p.m.: Tour ends/Lunch
      • 1:30 p.m.: Visit ends

    The tour of the facilities will be the most visual portion of the visit.


    Sandia National Laboratories is a multimission laboratory operated by National Technology and Engineering Solutions of Sandia LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration. Sandia Labs has major research and development responsibilities in nuclear deterrence, global security, defense, energy technologies and economic competitiveness, with main facilities in Albuquerque, New Mexico, and Livermore, California.

    Sandia news media contact: 

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