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Tag: American Chemical Society (ACS)

  • Rubber plumbing seals can leak additives into drinking water, study says

    Rubber plumbing seals can leak additives into drinking water, study says

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    Newswise — As drinking water flows through pipes and into a glass, it runs against the rubber seals inside some plumbing devices. These parts contain additives that contribute to their flexibility and durability, but these potentially harmful compounds can leak into drinking water, according to a small-scale study in ACS’ Environmental Science & Technology Letters. The authors report that the released compounds, which are typically linked to tire pollution, also transformed into other unwanted byproducts.

    To enhance rubber’s strength and durability, manufacturers typically mix in additives. Scientists have shown that tire dust can transport these substances, such as 1,3 diphenylguanidine (DPG) and N-(1,3-dimethylbutyl)-N’-phenyl-1,4-benzenediamine (6PPD), into waterways. DPG and 6PPD have also been detected in drinking water samples, though it’s unclear how the compounds got there. In previous research, Shane Snyder and Mauricius Marques dos Santos found that these rubber additives can react with disinfectants in simulated drinking water. Their lab tests generated a variety of chlorinated compounds, some of which could damage DNA. Now, the team wanted to assess whether real-world rubber plumbing fixtures can release DPG and 6PPD and form chlorinated byproducts in drinking water samples.

    In this pilot study, the team collected tap water from 20 buildings and detected polymer additives at parts per trillion levels in every sample. The researchers explain that these compounds are not currently regulated, but the measured levels are potentially concerning, based on their previous study’s results from human cell bioassays. And the samples from faucets with aerators contained the highest total amounts. All of the samples contained DPG and one of its chlorinated byproducts, whereas 6PPD and two other chlorine-containing compounds were each found in fewer than five samples. This is the first report of chlorinated DPG byproducts in drinking water, according to the researchers.

    To see if these compounds could have come from plumbing fixtures, the team tested rubber O-rings and gaskets from seven commercial devices, including faucet aerators and connection seals. In the experiment, the rings sat in water with or without chlorinated disinfectants for up to two weeks. Most of the seals, except for the silicone-based ones, released DPG and 6PPD additives. Additionally, plumbing pieces sitting in disinfectant-treated water generated chlorinated forms of DPG in amounts that were consistent with those observed in the drinking water samples. Because some of the rubber plumbing seals released DPG and 6PPD, the researchers say that drinking water, as well as tire pollution, could be a route of human exposure to these compounds.

    The authors acknowledge funding from the Merlion programme; the French Ministry of Europe and Foreign Affairs; the Nanyang Technological University; the National Research Foundation of Singapore; and the Public Utilities Board, Singapore’s National Water Agency.

    The paper’s abstract will be available on Sept. 6 at 8 a.m. Eastern time here: http://pubs.acs.org/doi/abs/10.1021/acs.estlett.3c00446

    The American Chemical Society (ACS) is a nonprofit organization chartered by the U.S. Congress. ACS’ mission is to advance the broader chemistry enterprise and its practitioners for the benefit of Earth and all its people. The Society is a global leader in promoting excellence in science education and providing access to chemistry-related information and research through its multiple research solutions, peer-reviewed journals, scientific conferences, eBooks and weekly news periodical Chemical & Engineering News. ACS journals are among the most cited, most trusted and most read within the scientific literature; however, ACS itself does not conduct chemical research. As a leader in scientific information solutions, its CAS division partners with global innovators to accelerate breakthroughs by curating, connecting and analyzing the world’s scientific knowledge. ACS’ main offices are in Washington, D.C., and Columbus, Ohio.

    To automatically receive news releases from the American Chemical Society, contact [email protected].

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  • Talented 12: Chemical & Engineering News announces its 2023 rising stars in chemistry

    Talented 12: Chemical & Engineering News announces its 2023 rising stars in chemistry

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    Newswise — Chemical & Engineering News (C&EN), an independent news outlet of the American Chemical Society (ACS), has unveiled its annual “Talented 12” list. The list highlights early-career researchers in the chemical sciences who are fearlessly tackling difficult global problems. These intrepid innovators in chemistry are featured in the May 19 issue of C&EN; read about the impressive class by visiting https://cenm.ag/t12-2023.

    Using a rigorous review process, C&EN selected this year’s Talented 12 from a highly competitive pool. The world-changing work by this year’s group includes research with a variety of applications from medicinal chemistry to investigations of energy to improving sustainable practices.

    Below is the list of 2023’s Talented 12 class.

         Iwnetim Iwnetu Abate, Massachusetts Institute of Technology
         This materials scientist engineers new electrode materials for energy applications.

         Alex Abela, Vertex Pharmaceuticals
         This medicinal chemist makes life-changing molecules for treating cystic fibrosis. 

         Athina Anastasaki, Swiss Federal Institute of Technology (ETH), Zurich
         This materials chemist shows prowess for pulling polymers apart. 

         Maxx Arguilla, University of California, Irvine
         This materials chemist creates atom-thin wires and sheets with exciting electronic and optical properties.

         Evelyn Auyeung, Dow
         This catalyst specialist wants to create plastics that are easier to recycle.

         Susannah Banziger, Corteva Agriscience
         This formulation chemist uses automation to make agrochemicals more sustainable.

         Marina Evich, U.S. Environmental Protection Agency
         This environmental chemist finds new ways to track down contaminants in soil and water. 

         Raúl Hernández Sánchez, Rice University
         This supramolecular chemist uses molecular assemblies to purify water and develop clean energy catalysts.

         Stacy Malaker, Yale University
         This mass spectrometrist develops methods to study challenging sugar-coated proteins. 

         Ben Ofori-Okai, SLAC National Accelerator Laboratory
         This spectroscopist develops innovative instrumentation to study how matter behaves at the center of planets. 

         Ezgi Toraman, Pennsylvania State University
         This chemical engineer studies technologies that turn waste into fuels, chemicals and other products. 

         Charlotte Vogt, Technion – Israel Institute of Technology
         This spectroscopist probes catalysts to accelerate the world’s transition to clean energy.

    “I loved reading about the chemists chosen as C&EN’s Talented 12 this year, and I know our audience will too,” says Michael McCoy, C&EN interim editor in chief. “These young scientists are making a mark on the world, both through their research and through outreach to the communities they live in or come from. They reassure me that chemistry will play a role in solving some of our planet’s most pressing problems.”

    Members of the Talented 12 will speak about their work and their journeys during a symposium on Aug. 14, at ACS Fall 2023 in San Francisco. If you are interested in obtaining headshots of any of the Talented 12, please contact [email protected]

    Do you know a talented chemist who fits the Talented 12 bill? Nominate someone to be considered as a member of next year’s Talented 12 here: https://cenm.ag/t12-nominations-2024. Nominations are due by Jan. 16, 2024.

    The American Chemical Society (ACS) is a nonprofit organization chartered by the U.S. Congress. ACS’ mission is to advance the broader chemistry enterprise and its practitioners for the benefit of Earth and all its people. The Society is a global leader in promoting excellence in science education and providing access to chemistry-related information and research through its multiple research solutions, peer-reviewed journals, scientific conferences, eBooks and weekly news periodical Chemical & Engineering News. ACS journals are among the most cited, most trusted and most read within the scientific literature; however, ACS itself does not conduct chemical research. As a leader in scientific information solutions, its CAS division partners with global innovators to accelerate breakthroughs by curating, connecting and analyzing the world’s scientific knowledge. ACS’ main offices are in Washington, D.C., and Columbus, Ohio.

    To automatically receive news releases from the American Chemical Society, contact [email protected].

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  • Fermented coffee’s fruity aromas demystified

    Fermented coffee’s fruity aromas demystified

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    Newswise — INDIANAPOLIS, March 29, 2023 — Specialty coffees are gaining traction in coffeehouses around the world — and now a fermented version could bring a fruity taste to your morning cup of joe. This new kind of beverage has a raspberry-like taste and aroma, but what causes these sensations has been a mystery. Today, scientists report six compounds that contribute to the fermented coffee experience. The work could help increase production of the drink and make it more readily available for everyone to enjoy.

    The researchers will present their results at the spring meeting of the American Chemical Society (ACS). ACS Spring 2023 is a hybrid meeting being held virtually and in-person March 26–30, and features more than 10,000 presentations on a wide range of science topics.

    “There are now flavors that people are creating that no one would have ever associated with coffee in the past,” says Chahan Yeretzian, Ph.D., the project’s principal investigator. “The flavors in fermented coffee, for example, are often more akin to fruit juices.”

    This unusual type of beverage provides a unique flavor experience for consumers, and the growing demand for it means that fermented coffee beans can fetch a high price, potentially benefiting farmers. And the process by which the beans are prepared requires much less water than traditional methods, making it a more environmentally friendly alternative to a standard cup of coffee.

    But despite this drink’s growing popularity, the compounds that cause its distinctive flavor were unknown. And with fermented coffee becoming more popular in competitive events, some people have been concerned that the lack of knowledge about fermented coffee may make it difficult to distinguish between the genuine product and regular joe that has been illicitly adulterated. So, Yeretzian and colleagues from the Coffee Excellence Center at Zurich University of Applied Sciences sought to identify the compounds that are responsible for these new and exciting flavors. And because flavor and smell are intimately linked, studying the beverages’ scents could help the team gain a better understanding of how fermented coffee’s complex flavor is created.

    To single out the compounds unique to fermented coffee’s aromas, researchers took arabica beans and divided them into three groups. One was prepared using a wash process, which is likely how your average afternoon pick-me-up brew is made. Here, a gelatinous substance known as mucilage is stripped from the coffee bean, which is washed with water before being dried. The researchers prepared the second group using the pulped natural process — another common approach — in which the skin is removed from the bean, but the mucilage is left intact. Finally, the team fermented beans in the third group using carbonic maceration, a process often used in winemaking. This method was first introduced to the specialty coffee world in 2015, when the winning contestant in the World Barista Championship used it to prepare their entry. With this process, whole coffee fruits are fermented in stainless steel tanks and infused with carbon dioxide to lower the pH of the fermentation. Unlike the other brews, the coffee made with fermented beans was described as smelling intense, like raspberries with a hint of rose.

    Next, the researchers brewed coffee using each type of bean and analyzed the samples with gas chromatography (GC) sniffing, also called GC olfactometry. First, the GC instrument separated individual components in the air above each sample. Then, as the compounds left the instrument, they went to a mass spectrometer for identification, and to someone sitting at the outlet to describe what they smelled.

    “Because the chemical signature doesn’t tell us how a compound smells, we have to rely on the human nose to detect the scent as each compound comes out of the chromatography instrument individually,” says Yeretzian. This methodology can be tricky because there is a subjective element to it. “We’re using people to detect scents, and everybody perceives flavors a little differently,” says Samo Smrke, Ph.D., a research associate in the lab who is presenting the results. “But in this case, the panel was very consistent in the smells they described. So, what is traditionally considered a challenge was actually not an issue because the aromas were so clear.”

    There is one major advantage to GC sniffing. The human nose can sometimes detect scents from compounds that are at such a low concentration, they’re unable to be picked up by mass spectrometry. In this case, although six compounds appeared to contribute to the intense fruity flavor and the raspberry scent of the fermented coffee, the team was only able to identify three of them: 2-methylpropanal, 3-methylbutanal and ethyl 3-methylbutanoate.

    In the future, the researchers hope to identify the remaining compounds, as well as judge the intensity of different flavors and scents. Additionally, the researchers would like to know more about how these unique compounds form. Potential factors include farming practices, the variety of coffee beans, the microclimate of specific farms and the microbes present during fermentation. “There’s still quite a lot of unknowns surrounding this process,” says Smrke. A better understanding of the sources of these compounds could help the team standardize production methods, making it easier to produce fermented coffee at larger scales and allowing even more people to enjoy this distinctive flavor.

    The researchers acknowledge support and funding from Project Origin Australia and Zurich University of Applied Sciences.

    A recorded media briefing on this topic will be posted Wednesday, March 29, by 10 a.m. Eastern time at www.acs.org/acsspring2023briefings. Reporters can request access to media briefings during the embargo period by contacting [email protected].

    For health and safety information for ACS Spring 2023, please visit the FAQ webpage.  

    The American Chemical Society (ACS) is a nonprofit organization chartered by the U.S. Congress. ACS’ mission is to advance the broader chemistry enterprise and its practitioners for the benefit of Earth and all its people. The Society is a global leader in promoting excellence in science education and providing access to chemistry-related information and research through its multiple research solutions, peer-reviewed journals, scientific conferences, eBooks and weekly news periodical Chemical & Engineering News. ACS journals are among the most cited, most trusted and most read within the scientific literature; however, ACS itself does not conduct chemical research. As a leader in scientific information solutions, its CAS division partners with global innovators to accelerate breakthroughs by curating, connecting and analyzing the world’s scientific knowledge. ACS’ main offices are in Washington, D.C., and Columbus, Ohio.

    To automatically receive news releases from the American Chemical Society, contact [email protected].

    Note to journalists: Please report that this research was presented at a meeting of the American Chemical Society.

    Follow us: Twitter | Facebook | LinkedIn | Instagram

    Title
    Exploring unique coffee flavours of fermented high-end specialty coffee: Towards the fourth wave coffee 

    Abstract
    Third wave coffee has its origin in the 1970s when coffee businesses started sourcing high-quality specialty coffee and delivering it freshly roasted to consumers. Over the past decade specialty coffee has become ubiquitous, and its market share has continuously grown. Presently, there is no consensus about what the fourth wave could be like. One of the developments has been the emergence of heavily fermented coffees. These exhibit very characteristic, clearly defined, and intense aromas and command a price up to 100-times higher than the commodity market price. Arabica coffee from the farm Iris Estate, Geisha variety, has been post-harvest processed by three methods: washed (W), pulped natural (PN), and fermented by so-called ‘carbonic maceration’ (CM). The aim was to elucidate the impact of CM on the flavour profile, as compared to the W and PN process. Sensory evaluation had revealed that CM creates characteristic flavour notes that were described as raspberry with hint of rose water. The aroma compounds of the roasted and ground coffee were analysed using solid-phase micro extraction gas chromatography (SPME-GC) and detected by both sniffing (GC-O) and mass spectrometry (GC-MS). The study found six compounds that are considered contributing to the characteristic raspberry flavour of the CM coffee. These compounds were consistently identified as intense with raspberry notes when sniffing CM coffee, but not in W coffee. Three out of the six were identified and characterized by means of MS, whereas the other three were detected only by GC-O and could not be characterised by MS. The link of an experimental fermentation post-harvest processing technique to characteristic flavour compounds and sensory notes in the cup could be established. Such studies may ultimately allow such coffees to become scalable and more readily available for everyone to experience and enjoy.

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  • Human cells help researchers understand squid camouflage

    Human cells help researchers understand squid camouflage

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    INDIANAPOLIS, March 27, 2023 — Squids and octopuses are masters of camouflage, blending into their environment to evade predators or surprise prey. Some aspects of how these cephalopods become reversibly transparent are still “unclear,” largely because researchers can’t culture cephalopod skin cells in the lab. Today, however, researchers report that they have replicated the tunable transparency of some squid skin cells in mammalian cells, which can be cultured. The work could not only shed light on basic squid biology, but also lead to better ways to image many cell types. 

    The researchers will present their results at the spring meeting of the American Chemical Society (ACS). ACS Spring 2023 is a hybrid meeting being held virtually and in-person March 26–30, and features more than 10,000 presentations on a wide range of science topics. 

    For many years, Alon Gorodetsky, Ph.D., and his research group have been working on materials inspired by squid. In past work, they developed “invisibility stickers,” which consisted of bacterially produced squid reflectin proteins that were adhered onto sticky tape. “So then, we had this crazy idea to see whether we could capture some aspect of the ability of squid skin tissues to change transparency within human cell cultures,” says Gorodetsky, who is the principal investigator on the project.

    The team at the University of California, Irvine focused their efforts on cephalopod cells called leucophores, which have particulate-like nanostructures composed of reflectin proteins that scatter light. Typically, reflectins clump together and form the nanoparticles, so light isn’t absorbed or directly transmitted; instead, the light scatters or bounces off of them, making the leucophores appear bright white.

    “We wanted to engineer mammalian cells to stably, instead of temporarily, form reflectin nanostructures for which we could better control the scattering of light,” says Gorodetsky. That’s because if cells allow light through with little scattering, they’ll seem more transparent. Alternatively, by scattering a lot more light, cells will become opaque and more apparent. “Then, at a cellular level, or even the culture level, we thought that we could predictably alter the cells’ transparency relative to the surroundings or background,” he says.

    To change how light interacts with cultured cells, Georgii Bogdanov, a graduate student in Gorodetsky’s lab who is presenting the results, introduced squid-derived genes that encoded for reflectin into human cells, which then used the DNA to produce the protein. “A key advance in our experiments was getting the cells to stably produce reflectin and form light-scattering nanostructures with relatively high refractive indices, which also allowed us to better image the cells in three dimensions,” says Bogdanov.

    In experiments, the team added salt to the cells’ culture media and observed the reflectin proteins clumping together into nanostructures. By systematically increasing the salt concentration, Bogdanov got detailed, time-lapse 3D images of the nanostructures’ properties. As the nanoparticles became larger, the amount of light that bounced off the cells increased, consequently tuning their opacity.

    Then, the COVID-19 pandemic hit, leaving the researchers to wonder what they could do to advance their investigation without being physically in the lab. So, Bogdanov spent his time at home developing computational models that could predict a cell’s expected light scattering and transparency before an experiment was even run. “It’s a beautiful loop between theory and experiments, where you feed in design parameters for the reflectin nanostructures, get out specific predicted optical properties and then engineer the cells more efficiently — for whatever light-scattering properties you might be interested in,” explains Gorodetsky.

    On a basic level, Gorodetsky suggests that these results will help scientists better understand squid skin cells, which haven’t been successfully cultured in a laboratory setting. For example, previous researchers postulated that reflectin nanoparticles disassemble and reassemble to change the transparency of tunable squid leucophores. And now Gorodetsky’s team has shown that similar rearrangements occurred in their stable engineered mammalian cells with simple changes in salt concentration, a mechanism that appears analogous to what has been observed in the tunable squid cells.

    The researchers are now optimizing their technique to design better cellular imaging strategies based on the cells’ intrinsic optical properties. Gorodetsky envisions that the reflectin proteins could act as genetically encoded tags that would not bleach inside human cells. “Reflectin as a molecular probe provides a lot of possibilities to track structures in cells with advanced microscopy techniques,” adds Bogdanov. For example, the scientists propose that imaging approaches based on their work could also have implications for better understanding cell growth and development.

    The researchers acknowledge funding from the Defense Advanced Research Projects Agency and the U.S. Air Force Office of Scientific Research.

    A recorded media briefing on this topic will be posted Monday, March 27, by 10 a.m. Eastern time at www.acs.org/acsspring2023briefings. Reporters can request access to media briefings during the embargo period by contacting [email protected].

    For health and safety information for ACS Spring 2023, please visit the FAQ webpage.  

    The American Chemical Society (ACS) is a nonprofit organization chartered by the U.S. Congress. ACS’ mission is to advance the broader chemistry enterprise and its practitioners for the benefit of Earth and all its people. The Society is a global leader in promoting excellence in science education and providing access to chemistry-related information and research through its multiple research solutions, peer-reviewed journals, scientific conferences, eBooks and weekly news periodical Chemical & Engineering News. ACS journals are among the most cited, most trusted and most read within the scientific literature; however, ACS itself does not conduct chemical research. As a leader in scientific information solutions, its CAS division partners with global innovators to accelerate breakthroughs by curating, connecting and analyzing the world’s scientific knowledge. ACS’ main offices are in Washington, D.C., and Columbus, Ohio.

    To automatically receive news releases from the American Chemical Society, contact [email protected].

    Note to journalists: Please report that this research was presented at a meeting of the American Chemical Society.

    Follow us: Twitter | Facebook | LinkedIn | Instagram

    Title
    Dynamic optical systems inspired by cephalopods 

    Abstract
    Cephalopods (e.g., squids, octopuses, and cuttlefish) have captivated the imagination of both the general public and scientists alike due to their sophisticated nervous systems, complex behavioral patterns, and visually stunning coloration changes. By drawing inspiration from the structures and functionalities of tunable cephalopod skin cells, we have designed and engineered human cells that contain reconfigurable protein-based photonic architectures and, as a result, possess tunable transparency-changing and light-scattering capabilities (1). In turn, we have visualized the refractive index distributions of analogous engineered cells with three-dimensional label-free holotomographic microscopy techniques, and as a consequence, we have developed a detailed understanding of the relationship between their global optical characteristics and subcellular ultrastructures (2). We have moreover extended these efforts to the predictive engineering of the refractive indices and light-scattering properties of multiple self-assembled protein-based platforms, both in vitro and in vivo (2,3). Finally, we have developed improved chemical and genetic strategies for manipulating the sizes, numbers, and refractive indices of our subcellular structures (4). Our combined findings may facilitate an improved understanding of cephalopod camouflage mechanisms and lead to the development of unique tools for applications in biophotonics and bioengineering.

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  • Colorful films could help buildings, cars keep their cool

    Colorful films could help buildings, cars keep their cool

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    Newswise — INDIANAPOLIS, March 26, 2023 — The cold blast of an air conditioner can be a welcome relief as temperatures soar, but “A/C” units require large amounts of energy and can leak potent greenhouse gases. Today, scientists report an eco-friendly alternative — a plant-based film that gets cooler when exposed to sunlight and comes in a variety of textures and bright, iridescent colors. The material could someday keep buildings, cars and other structures cool without requiring external power.

    The researchers will present their results at the spring meeting of the American Chemical Society (ACS). ACS Spring 2023 is a hybrid meeting being held virtually and in-person March 26–30 and features more than 10,000 presentations on a wide range of science topics.

    “To make materials that remain cooler than the air around them during the day, you need something that reflects a lot of solar light and doesn’t absorb it, which would transform energy from the light into heat,” says Silvia Vignolini, Ph.D., the project’s principal investigator. “There are only a few materials that have this property, and adding color pigments would typically undo their cooling effects,” Vignolini adds.

    Passive daytime radiative cooling (PDRC) is the ability of a surface to emit its own heat into space without it being absorbed by the air or atmosphere. The result is a surface that, without using any electrical power, can become several degrees colder than the air around it. When used on buildings or other structures, materials that promote this effect can help limit the use of air conditioning and other power-intensive cooling methods.

    Some paints and films currently in development can achieve PDRC, but most of them are white or have a mirrored finish, says Qingchen Shen, Ph.D., who is presenting the work at the meeting. Both Vignolini and Shen are at Cambridge University (U.K.). But a building owner who wanted to use a blue-colored PDRC paint would be out of luck — colored pigments, by definition, absorb specific wavelengths of sunlight and only reflect the colors we see, causing undesirable warming effects in the process.

    But there’s a way to achieve color without the use of pigments. Soap bubbles, for example, show a prism of different colors on their surfaces. These colors result from the way light interacts with differing thicknesses of the bubble’s film, a phenomenon called structural color. Part of Vignolini’s research focuses on identifying the causes behind different types of structural colors in nature. In one case, her group found that cellulose nanocrystals (CNCs), which are derived from the cellulose found in plants, could be made into iridescent, colorful films without any added pigment.

    As it turns out, cellulose is also one of the few naturally occurring materials that can promote PDRC. Vignolini learned this after hearing a talk from the first researchers to have created a cooling film material. “I thought wow, this is really amazing, and I never really thought cellulose could do this.”

    In recent work, Shen and Vignolini layered colorful CNC materials with a white-colored material made from ethyl cellulose, producing a colorful bi-layered PDRC film. They made films with vibrant blue, green and red colors that, when placed under sunlight, were an average of nearly 40 F cooler than the surrounding air. A square meter of the film generated over 120 Watts of cooling power, rivaling many types of residential air conditioners. The most challenging aspect of this research, Shen says, was finding a way to make the two layers stick together — on their own, the CNC films were brittle, and the ethyl cellulose layer had to be plasma-treated to get good adhesion. The result, however, was films that were robust and could be prepared several meters at a time in a standard manufacturing line.

    Since creating these first films, the researchers have been improving their aesthetic appearance. Using a method modified from approaches previously explored by the group, they’re making cellulose-based cooling films that are glittery and colorful. They’ve also adjusted the ethyl cellulose film to have different textures, like the differences between types of wood finishes used in architecture and interior design, says Shen. These changes would give people more options when incorporating PDRC effects in their homes, businesses, cars and other structures.

    The researchers now plan to find ways they can make their films even more functional. According to Shen, CNC materials can be used as sensors to detect environmental pollutants or weather changes, which could be useful if combined with the cooling power of their CNC-ethyl cellulose films. For example, a cobalt-colored PDRC on a building façade in a car-dense, urban area could someday keep the building cool and incorporate detectors that would alert officials to higher levels of smog-causing molecules in the air.

    The researchers acknowledge support and funding from Purdue University, the American Society of Mechanical Engineers, the European Research Council, the Engineering and Physical Sciences Research Council, the Biotechnology and Biological Sciences Research Council, the European Union and Shanghai Jiao Tong University.

    A recorded media briefing on this topic will be posted Monday, March 27, by 10 a.m. Eastern time at www.acs.org/acsspring2023briefings. Reporters can request access to media briefings during the embargo period by contacting [email protected].

    For health and safety information for ACS Spring 2023, please visit the FAQ webpage.

    The American Chemical Society (ACS) is a nonprofit organization chartered by the U.S. Congress. ACS’ mission is to advance the broader chemistry enterprise and its practitioners for the benefit of Earth and all its people. The Society is a global leader in promoting excellence in science education and providing access to chemistry-related information and research through its multiple research solutions, peer-reviewed journals, scientific conferences, eBooks and weekly news periodical Chemical & Engineering News. ACS journals are among the most cited, most trusted and most read within the scientific literature; however, ACS itself does not conduct chemical research. As a leader in scientific information solutions, its CAS division partners with global innovators to accelerate breakthroughs by curating, connecting and analyzing the world’s scientific knowledge. ACS’ main offices are in Washington, D.C., and Columbus, Ohio.

    To automatically receive news releases from the American Chemical Society, contact [email protected].

    Note to journalists: Please report that this research was presented at a meeting of the American Chemical Society.

    Follow us: Twitter | Facebook | LinkedIn | Instagram

    Title
    Structurally colored radiative cooling cellulosic films 

    Abstract
    Daytime radiative cooling (DRC) materials offer a sustainable approach to thermal management by exploiting net positive heat transfer to deep space. While such materials typically have a white or mirror-like appearance to maximize solar reflection, extending the palette of available colors is required to promote their real-world utilization. However, the incorporation of conventional absorption-based colorants inevitably leads to solar heating, which counteracts any radiative cooling effect. In this work, efficient sub-ambient DRC (Day: −4 °C, Night: −11 °C) from a vibrant, structurally colored film prepared from naturally derived cellulose nanocrystals (CNCs), is instead demonstrated. Arising from the underlying photonic nanostructure, the film selectively reflects visible light resulting in intense, fade-resistant coloration, while maintaining a low solar absorption (~3%).  Additionally, a high emission within the mid-infrared atmospheric window (>90%) allows for significant radiative heat loss. By coating such CNC films onto a highly scattering, porous ethylcellulose (EC) base layer, any sunlight that penetrates the CNC layer is backscattered by the EC layer below, achieving broadband solar reflection and vibrant structural color simultaneously. Finally, scalable manufacturing using a commercially relevant roll-to-roll process validates the potential to produce such colored radiative cooling materials at a large scale from a low-cost and sustainable feedstock.

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  • What do the elements sound like? (video)

    What do the elements sound like? (video)

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    Newswise — INDIANAPOLIS, March 26, 2023 — In chemistry, we have He, Fe and Ca — but what about do, re and mi? Hauntingly beautiful melodies aren’t the first things that come to mind when looking at the periodic table of the elements. However, using a technique called data sonification, a recent college graduate has converted the visible light given off by the elements into audio, creating unique, complex sounds for each one. Today, the researcher reports the first step toward an interactive, musical periodic table.

    The researcher will present his results at the spring meeting of the American Chemical Society (ACS). ACS Spring 2023 is a hybrid meeting being held virtually and in-person March 26–30, and features more than 10,000 presentations on a wide range of science topics.

    A video on the research is available at www.acs.org/elementmusic.

    Previously, W. Walker Smith, the project’s sole investigator, took his combined passions of music and chemistry and converted the natural vibrations of molecules into a musical composition. “Then I saw visual representations of the discrete wavelengths of light released by the elements, such as scandium,” says Smith. “They were gorgeous and complex, and I thought, ‘Wow, I really want to turn these into music, too.’”

    Elements emit visible light when they are energized. This light is made up of multiple individual wavelengths, or particular colors, with brightness levels that are unique for each element. But on paper, the collections of wavelengths for different elements are hard to tell apart visually, especially for the transition metals, which can have thousands of individual colors, says Smith. Converting the light into sound frequencies could be another way for people to detect the differences between elements.

    However, creating sounds for the elements on the periodic table has been done before. For instance, other scientists have assigned the brightest wavelengths to single notes played by the keys on a traditional piano. But this approach reduced the rich variety of wavelengths released by some elements into just a few sounds, explains Smith, who is currently a researcher at Indiana University.

    To retain as much of the complexity and nuance of the element spectra as possible, Smith consulted faculty mentors at Indiana University, including David Clemmer, Ph.D., a professor in the chemistry department, and Chi Wang, D.M.A., a professor in the Jacobs School of Music. With their assistance, Smith built a computer code for real-time audio that converted each element’s light data into mixtures of notes. The discrete color wavelengths became individual sine waves whose frequency corresponded to that of the light, and their amplitude matched the brightness of the light.

    Early in the research process, Clemmer and Smith discussed the pattern similarities between light and sound vibrations. For instance, within the colors of visible light, violet has almost double the frequency of red, and in music, one doubling of frequency corresponds to an octave. Therefore, visible light can be thought of as an “octave of light.” But this octave of light is at a much higher frequency than the audible range. So, Smith scaled the sine waves’ frequencies down by approximately 10-12, fitting the audio output into a range where human ears are most sensitive to differences in pitch.

    Because some elements had hundreds or thousands of frequencies, the code allowed these notes to be generated in real time, forming harmonies and beating patterns as they mixed together. “The result is that the simpler elements, such as hydrogen and helium, sound vaguely like musical chords, but the rest have a more complex collection of sounds,” says Smith. For example, calcium sounds like bells chiming together with a rhythm resulting from how the frequencies interact with each other. Listening to the notes from some other elements reminded Smith of a spooky background noise, similar to music used in cheesy horror movies. He was especially surprised by the element zinc, which despite having a large number of colors, sounded like “an angelic choir singing a major chord with vibrato.”

    “Some of the notes sound out of tune, but Smith has kept true to that in this translation of the elements into music,” says Clemmer. These off-key tones — known musically as microtones — come from frequencies that are found between the keys of a traditional piano. Agreeing, Wang says, “The decisions as to what’s vital to preserve when doing data sonification are both challenging and rewarding. And Smith did a great job making such decisions from a musical standpoint.”

    The next step is to turn this technology into a new musical instrument with an exhibit at the WonderLab Museum of Science, Health, and Technology in Bloomington, Indiana. “I want to create an interactive, real-time musical periodic table, which allows both children and adults to select an element and see a display of its visible light spectrum and hear it at the same time,” says Smith. He adds that this sound-based approach has potential value as an alternative teaching method in chemistry classrooms, because it’s inclusive to people with visual impairments and different learning styles.

    On Tuesday, March 28, at 3:00 p.m., during the ACS Spring 2023 Meeting, Smith will also perform “The Sound of Molecules,” a show that will feature audio clips of a few of the elements, as well as “compositions” of larger molecules.

    Smith acknowledges support and funding from Indiana University’s Department of Chemistry, Center for Electronic and Computer Music, and Center for Rural Engagement; an Indiana University Undergraduate Research grant; the 2022 Annual Project Jumpstart Innovation Competition; and the Indiana University Hutton Honors College Grant Program.

    A recorded media briefing on this topic will be posted Monday, March 27, by 10 a.m. Eastern time at www.acs.org/acsspring2023briefings. Reporters can request access to media briefings during the embargo period by contacting [email protected].

    For health and safety information for ACS Spring 2023, please visit the FAQ webpage.

    The American Chemical Society (ACS) is a nonprofit organization chartered by the U.S. Congress. ACS’ mission is to advance the broader chemistry enterprise and its practitioners for the benefit of Earth and all its people. The Society is a global leader in promoting excellence in science education and providing access to chemistry-related information and research through its multiple research solutions, peer-reviewed journals, scientific conferences, eBooks and weekly news periodical Chemical & Engineering News. ACS journals are among the most cited, most trusted and most read within the scientific literature; however, ACS itself does not conduct chemical research. As a leader in scientific information solutions, its CAS division partners with global innovators to accelerate breakthroughs by curating, connecting and analyzing the world’s scientific knowledge. ACS’ main offices are in Washington, D.C., and Columbus, Ohio.

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    Title
    Designing an interactive musical periodic table: sonification of visible element emission spectra 

    Abstract

    What does the element helium sound like? What about hydrogen? While these may seem like absurd questions, the process of data sonification can be used to convert the visible spectra of chemical elements into sounds. When stimulated by electricity or heat, elements release distinct wavelengths of light depending on their electron energy levels—a sort of “chemical footprint” unique to every element. These frequencies of light, which we perceive as different colors, can be scaled into the audio range to yield different sonic frequencies, allowing one to hear the different sounds of chemical elements. This research project involved the construction of an interactive musical periodic table, combining musical and visual representations of elemental spectra from high-resolution spectral datasets.

    The interactive periodic table was designed using Max/MSP, a programming language that uses digital signal processing (DSP) algorithms to generate real-time audio and visual outputs. This allows all spectral lines of an element to be played simultaneously (as a “chord”) or for individual lines to be played in succession (as a “melody”). This highly interdisciplinary project has applications spanning data analysis, STEAM (STEM + Arts) education, and public science outreach. Sonification of scientific data provides alternative methods of analysis that can expand access of such data to blind and visually impaired people. Sonification can even enhance data analysis via traditional data visualization by providing a supplementary layer of auditory information, and sonification-based learning models have been shown to improve student engagement and understanding of scientific concepts like protein folding.

    This program is currently being implemented in several middle and high school music and science classes, as well as a public music/science show titled “The Sound of Molecules” at WonderLab Museum of Science. Future work will focus on designing a free and open-source version of the program that does not require specialized DSP software.

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  • American Chemical Society announces new CEO: Albert G. Horvath

    American Chemical Society announces new CEO: Albert G. Horvath

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    Newswise — The American Chemical Society (ACS) Board of Directors has selected Albert G. Horvath, Treasurer and Chief Financial Officer (CFO) at ACS, as the Society’s next CEO, effective Jan. 1, 2023. He succeeds Thomas Connelly Jr., who is retiring after nearly eight years with ACS.

    “I am pleased that a person with Al Horvath’s skill will be the next CEO of ACS,” says Paul W. Jagodzinski, chair of the ACS Board of Directors. “His dedication to the mission and core values of ACS, coupled with his experience in member and public-serving organizations, position him well to lead the Society as we move forward.”

    “I am honored and humbled to have been selected for this role and greatly appreciative to the Board for its confidence in me,” says Horvath. “I have developed a deep commitment to ACS, and I look forward to working with our talented team in serving our members, customers and the entire chemistry enterprise. Together with our volunteers, I am confident that we will achieve the Society’s bold vision.”

    Prior to joining ACS in 2019, Horvath served as Chief Operating Officer and Under Secretary for Finance and Administration at the Smithsonian Institution. There, he oversaw more than 2,200 employees in various Smithsonian offices, including facilities and maintenance, human resources, security, commercial enterprises and financial operations. He joined the Smithsonian in 2011 and served as its Acting Secretary for six months in 2015. In this role, he worked closely with museum and research center directors to bring the Smithsonian’s vast resources — spanning history, art, culture and science — to the citizens of the U.S. and visitors from around the world.

    Horvath’s tenure at the Smithsonian was preceded by more than two decades working in senior leadership roles for some of the leading research universities in the country. He was the Vice President for Finance and Business at the Pennsylvania State University (Penn State), his alma mater, for two years before being named Senior Vice President for Finance and Business/Treasurer. He was responsible for financial, endowment, business and administrative activities at all Penn State campuses, with a $4.2 billion operating budget.

    Before joining Penn State, Horvath was Executive Vice President of Finance and CFO at Columbia University (2004–07), where he had oversight for all financial activities of the university, including the medical center, and developed a five-year capital plan and debt strategy. And prior to that, he worked at the California Institute of Technology, where he served as the Associate Vice President for Finance and Controller in 2000, before becoming the Vice President for Business and Finance/CFO in 2001, a position he held until joining Columbia University.

    From 1994 until 2000, he was Controller at New York University, having previously served in senior roles at Carnegie Mellon University (1988–94). He began his career at Mellon Bank (1981–88) in his hometown of Pittsburgh before moving into higher education.

    “Throughout his career, Al has held leadership roles in distinguished organizations committed to scientific advancement,” says Connelly. “His broad experience and personal qualities make him the ideal leader of ACS.”

    A native of Pennsylvania, Horvath earned his master’s degree in business administration at Duquesne University in 1985 and his bachelor’s degree in accounting at Penn State in 1981. He has served on numerous boards of directors, including the Smithsonian Channel, Green Door, Penn State Hershey Medical Center and Council on Governmental Relations, among others.

    The American Chemical Society (ACS) is a nonprofit organization chartered by the U.S. Congress. ACS’ mission is to advance the broader chemistry enterprise and its practitioners for the benefit of Earth and all its people. The Society is a global leader in promoting excellence in science education and providing access to chemistry-related information and research through its multiple research solutions, peer-reviewed journals, scientific conferences, eBooks and weekly news periodical Chemical & Engineering News. ACS journals are among the most cited, most trusted and most read within the scientific literature; however, ACS itself does not conduct chemical research. As a leader in scientific information solutions, its CAS division partners with global innovators to accelerate breakthroughs by curating, connecting and analyzing the world’s scientific knowledge. ACS’ main offices are in Washington, D.C., and Columbus, Ohio.

    To automatically receive news releases from the American Chemical Society, contact [email protected].

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